You can change which Envelope is connected to your Debt Account through the Add/Edit Accounts page. From that page, scroll down to the Debt Accounts section, then click “Edit” on the Debt Account whose Envelope you wish to change. The lower-left most dropdown option in the Debt Account edit menu will allow you to change the Envelope connected to that Account.
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You can either choose one of your existing Envelopes, or click the bottom “[NEW]” option to create a new Envelope for that Debt Account.